Upscaling of Mixing‐Limited Bimolecular Chemical Reactions in Poiseuille Flow
نویسندگان
چکیده
منابع مشابه
Propagation velocities of chemical reaction fronts advected by Poiseuille flow.
Poiseuille flow between parallel plates advects chemical reaction fronts, distorting them and altering their propagation velocities. Analytical solutions of the cubic reaction-diffusion-advection equation resolve the chemical concentration for narrow gaps, wide gaps, and small-amplitude flow. Numerical solutions supply a general description for fluid flow in the direction of propagation of the ...
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Fast reversible pseudo-unimolecular reactions do not approach equilibrium in the simple exponential fashion predicted by chemical rate equations. Many-body effects in bimolecular reactions have been revealed in an extensive series of Brownian simulations, showing up to three distinct phases in the approach to equilibrium. Recent theoretical developments are compared with the simulation as well ...
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ژورنال
عنوان ژورنال: Water Resources Research
سال: 2019
ISSN: 0043-1397,1944-7973
DOI: 10.1029/2018wr022730